Poly[diaqua-[3,5-bis-(trifluoro-meth-yl)pyrazolido]potassium].
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 8): m928, 2010 Jul 14.
Article
em En
| MEDLINE
| ID: mdl-21588161
ABSTRACT
The asymmetric unit of the title compound, [K(C(5)HF(6)N(2))(H(2)O)(2)](n), is composed of two 3,5-bis-(trifluoro-meth-yl)pyrazol-ide anions, two potassium cations and four water mol-ecules. The water mol-ecules and 3,5-bis-(trifluoro-meth-yl)pyrazolide anions act as bridges between the potassium cations. Each potassium cation is surrounded by four O atoms [K-O = 2.705â
(3)-2.767â
(3)â
Å] and four F atoms [K-F = 2.870â
(7)-3.215â
(13)â
Å]. The water mol-ecules and the 3,5-bis-(trifluoro-meth-yl)pyrazolide anions are connected by O-Hâ¯N hydrogen bonds, forming layers in the ab plane. All -CF(3) groups show rotational disorder between two orientations each.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2010
Tipo de documento:
Article