Voltammetric response of ferroceneboronic acid to diol and phenolic compounds as possible pollutants.
J Environ Sci (China)
; 23(6): 1027-32, 2011.
Article
em En
| MEDLINE
| ID: mdl-22066227
ABSTRACT
A voltammetric determination of possible organic pollutants such as diol and phenolic compounds in water was studied using ferroceneboronic acid (FBA) as a redox-active marker. A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0, respectively, while another pair of redox peaks was observed in the presence of diol or phenolic compounds tested. The results were rationalized based on the formation of boronate esters of FBA with the added compounds. The changes in the redox peak currents were dependent on the concentration of the additives, suggesting a usefulness of FBA in the electrochemical determination of these compounds in water.
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Base de dados:
MEDLINE
Assunto principal:
Fenóis
/
Poluentes da Água
/
Ácidos Borônicos
/
Compostos Ferrosos
/
Eletroquímica
Idioma:
En
Ano de publicação:
2011
Tipo de documento:
Article