Deracemization of bilirubin as the marker of the chirality of micellar aggregates.
Chirality
; 24(1): 78-85, 2012 Jan.
Article
em En
| MEDLINE
| ID: mdl-22121064
ABSTRACT
The deracemization of bilirubin in micellar aggregates of structurally correlated chiral surfactants was studied by circular dichroism experiments and exploited as the marker of the expression of chirality of the aggregates. The obtained results suggest that the hydrophobic interactions control the transfer of chirality from the monomers to the aggregates, and that different regions of the same aggregate might feature opposite enantiorecognition capabilities.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Bilirrubina
/
Micelas
Idioma:
En
Ano de publicação:
2012
Tipo de documento:
Article