catena-Poly[[[cis-aqua-dibromido-cobalt(II)]-µ-(pyrazine-2-carb-oxy-lic acid)-κN,O:N] monohydrate].
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 12): m1798-9, 2011 Dec 01.
Article
em En
| MEDLINE
| ID: mdl-22199583
ABSTRACT
The title compound, {[CoBr(2)(C(5)H(4)N(2)O(2))(H(2)O)]·H(2)O}(n), is a one-dimensional coordination polymer which crystallizes as a monohydrate. The asymmetric unit contains one Co(II) atom in a distorted octa-hedral geometry, forming a chain parallel to [010] with the pyrazine carb-oxy-lic acid ligands coordinating on one side in a bidentate fashion through one N and one O atom, and in a monodentate fashion through a N atom, with N atoms trans, and with both ligands lying in the same plane. The bromide atoms are cis to each other, while a water mol-ecule occupies the final octa-hedral coordination site. The chains are linked together though an O-Hâ¯Br hydrogen bonding network, and are further stabilized by an O-Hâ¯Br and O-Hâ¯O hydrogen-bonding framework with the solvent water mol-ecule.
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MEDLINE
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En
Ano de publicação:
2011
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Article