4-Meth-oxy-2-{(E)-[(thio-phen-2-yl)methyl-imino]-meth-yl}phenol.
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 9): o2801, 2012 Sep 01.
Article
em En
| MEDLINE
| ID: mdl-22969674
ABSTRACT
The title Schiff base, C(13)H(13)NO(2)S, adopts the phenol-imine tautomeric form and reveals an intra-molecular O-Hâ¯N hydrogen bond involving the hy-droxy group and the imino N atom, forming an S(6) ring. The mol-ecule is highly twisted with respect to the central imine group, which is reflected in the dihedral angle of 67.83â
(10)° formed by the thienyl and phenol rings. The crystal packing is characterized by weak C-Hâ¯O and C-Hâ¯π inter-actions.
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MEDLINE
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En
Ano de publicação:
2012
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Article