Solvent-free chemoselective oxidation of thioethers and thiophenes by mechanical milling.
Chem Commun (Camb)
; 48(95): 11632-4, 2012 Dec 11.
Article
em En
| MEDLINE
| ID: mdl-23095822
ABSTRACT
Organosulphur compounds can be easily and selectively oxidized to sulfones using a small excess of Oxone(®) (1.6 eq.) under solventless mechanical milling conditions. This green procedure has been efficiently applied to a series of model compounds and to the desulphurization of medium/high sulphur content paraffins (up to 3000 mg kg(-1)).
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MEDLINE
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En
Ano de publicação:
2012
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Article