Fabrication of large two-dimensional colloidal crystals via self-assembly in an attractive force gradient.
Langmuir
; 29(24): 7216-20, 2013 Jun 18.
Article
em En
| MEDLINE
| ID: mdl-23311289
ABSTRACT
Colloidal particles in a water-lutidine (WL) binary liquid mixture experience temperature-dependent attraction close to the mixture's demixing temperature. This temperature-tunable interaction can be potentially harnessed to assemble colloids and grow colloidal crystals. In this article, for the first time a novel attractive force gradient method is presented to fabricate high-quality, single-domain colloidal crystals. The well-controlled attractive force gradient here arises from a temperature gradient in the WL mixture. The nucleation of colloidal crystals in such a WL mixture preferably occurs in the high-temperature region because of the stronger attraction there. Crystallization propagates from the high-temperature region to the low-temperature region in a well-controlled way. The growth of the colloidal crystal is characterized in detail by Voronoi construction, the pair correlation function, and the orientational order parameter. It is found that the number of crystal-like particles increases with time, and a single-domain 2D colloidal crystal can be produced. The mechanism of the defect-free crystallization process is discussed on the basis of an analogy to cluster beam deposition methods. This study demonstrates an efficient and robust way to prepare colloidal crystals with little to no defects, being suitable for applications such as colloidal lithography and the fabrication of perfect 3D colloidal crystals.
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Base de dados:
MEDLINE
Assunto principal:
Coloides
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article