2-[5-(4-Fluoro-phen-yl)-3-(4-methyl-phen-yl)-4,5-dihydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thia-zole.
Acta Crystallogr Sect E Struct Rep Online
; 69(Pt 3): o392-3, 2013 Mar 01.
Article
em En
| MEDLINE
| ID: mdl-23476577
ABSTRACT
In the title compound, C25H20FN3S, two independent mol-ecules comprise the asymmetric unit, which differ in the relative orientation of the fluoro-benzene ring with respect to the pyrazole ring to which it is attached [dihedral angles = 89.39â
(17) and 75.23â
(16)° in the two mol-ecules]. Each pyrazole ring adopts an envelope conformation with the methine C atom being the flap atom. There are additional twists in the mol-ecules, e.g. between the five-membered rings [dihedral angles = 18.23â
(16) and 17.84â
(16)°] and between the thia-zole and attached phenyl ring [10.26â
(16) and 20.87â
(15)°]. Overall, each mol-ecule has a T-shape. In the crystal, mol-ecules are connected into a three-dimensional architecture by weak C-Hâ¯π inter-actions.
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MEDLINE
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En
Ano de publicação:
2013
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Article