Photocatalytic synthesis of allylic trifluoromethyl substituted styrene derivatives in batch and flow.
Org Lett
; 15(7): 1634-7, 2013 Apr 05.
Article
em En
| MEDLINE
| ID: mdl-23517196
ABSTRACT
A cobalt-catalyzed photochemical synthesis of allylic trifluoromethanes from styrene derivatives using 2,2,2-trifluoroethyl iodide is described. The method complements existing approaches, providing an alternative bond construction strategy to access these compounds. The process may be conducted in continuous mode in a novel photochemical flow reactor, resulting in a notable productivity increase.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Estirenos
/
Cobalto
/
Hidrocarbonetos Fluorados
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article