2-[3-(4-Bromo-phenyl)-5-(4-fluoro-phenyl)-4,5-di-hydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thia-zole.
Acta Crystallogr Sect E Struct Rep Online
; 69(Pt 5): o735, 2013 May 01.
Article
em En
| MEDLINE
| ID: mdl-23723887
In the title compound, C24H17BrFN3S, the pyrazole ring is almost planar (r.m.s. deviation = 0.043â
Å), with all but the perpendicular fluoro-benzene ring substituents [dihedral angle = 77.9â
(3)°] being very approximately coplanar [dihedral angle with the 2-thienyl ring = 19.4â
(3)° and with the bromo-benzene ring = 20.3â
(3)°; dihedral angle between the 2-thienyl and attached phenyl ring = 11.0â
(4)°], so that the mol-ecule has a T-shape. In the crystal, supra-molecular chains along the b-axis direction are sustained by C-Hâ¯S and C-Brâ¯π inter-actions.
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2013
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