Poly([1,4]Dithiino[2,3-c]Furan): the synthesis, electrochemistry, and optoelectronic properties of a furan-containing polymer.
Macromol Rapid Commun
; 34(16): 1330-4, 2013 Aug.
Article
em En
| MEDLINE
| ID: mdl-23877889
ABSTRACT
The chemical synthesis of a novel polyfuran, poly(2,3-bis(hexylthio)-[1,4]dithiino[2,3-c]furan) (PBDF), substituted at the 2,3-positions with an S-alkylated dithiin unit, is reported. The new polymer has been characterized in terms of its electronic absorption, electrochemical, and thermal properties. Employment of the dithiin moiety provides intrinsic additional electroactivity, as well as a functional handle for substitution with alkyl groups, enhancing the processability of the polymer. The new polymer is compared with the closely related and well-established literature compounds PEDOT and PEDTT as well-studied, highly chalcogenated polythiophenes.
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Base de dados:
MEDLINE
Assunto principal:
Polímeros
/
Eletrônica
/
Furanos
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article