Sputtered alumina as a novel stationary phase for micro machined gas chromatography columns.
Anal Bioanal Chem
; 406(4): 1245-7, 2014 Feb.
Article
em En
| MEDLINE
| ID: mdl-23989966
ABSTRACT
Silica and graphite sputtering have previously been reported as novel solid stationary phase deposition techniques for micro gas chromatography columns. As a conventional solid stationary phase in gas chromatography, compatible with sputtering yet so far unreported, alumina was evaluated in this study. Alumina sputtered semi-packed micro columns were fabricated (including an activation step) and proved able to separate a mixture of volatile alkanes (C1-C4 with isomers) in less than 1 min. Kinetic and a thermodynamic evaluation led to calculation of 4,500 theoretical plates for ethane in 1.1 m (HETPmin = 250 µm) and a Gibbs free energy for propane of 30.2 kJ mol(-1), making this stationary phase's properties very close to those observed with silica-sputtered micro columns.
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MEDLINE
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En
Ano de publicação:
2014
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Article