An unexpected copper catalyzed 'reduction' of an arylazide to amine through the formation of a nitrene intermediate.

Peng, Hanjing; Dornevil, Kednerlin H; Draganov, Alexander B; Chen, Weixuan; Dai, Chaofeng; Nelson, William H; Liu, Aimin; Wang, Binghe.

Afiliação

Peng H; Department of Chemistry, Center for Biotechnology and Drug Design, and Center for Diagnostics and Therapeutics, Georgia State University, P.O. Box 3965, Atlanta, Georgia 30302-3965, USA.
Dornevil KH; Department of Chemistry, Center for Biotechnology and Drug Design, and Center for Diagnostics and Therapeutics, Georgia State University, P.O. Box 3965, Atlanta, Georgia 30302-3965, USA.
Draganov AB; Department of Chemistry, Center for Biotechnology and Drug Design, and Center for Diagnostics and Therapeutics, Georgia State University, P.O. Box 3965, Atlanta, Georgia 30302-3965, USA.
Chen W; Department of Chemistry, Center for Biotechnology and Drug Design, and Center for Diagnostics and Therapeutics, Georgia State University, P.O. Box 3965, Atlanta, Georgia 30302-3965, USA.
Dai C; Department of Chemistry, Center for Biotechnology and Drug Design, and Center for Diagnostics and Therapeutics, Georgia State University, P.O. Box 3965, Atlanta, Georgia 30302-3965, USA.
Nelson WH; Department of Physics and Astronomy, Georgia State University, P.O. Box 4106, Atlanta, Georgia 30302-4106, USA.
Liu A; Department of Chemistry, Center for Biotechnology and Drug Design, and Center for Diagnostics and Therapeutics, Georgia State University, P.O. Box 3965, Atlanta, Georgia 30302-3965, USA.
Wang B; Department of Chemistry, Center for Biotechnology and Drug Design, and Center for Diagnostics and Therapeutics, Georgia State University, P.O. Box 3965, Atlanta, Georgia 30302-3965, USA.

Tetrahedron ; 69(25): 5079-5085, 2013 Jun 24.

Article em En | MEDLINE | ID: mdl-23997313