Imidazole-nitrile or imidazole-isonitrile C-C coupling on rhenium tricarbonyl complexes.
Chemistry
; 19(39): 12974-7, 2013 Sep 23.
Article
em En
| MEDLINE
| ID: mdl-24038657
ABSTRACT
Ligand activation Deprotonation of the nitrile or isonitrile complexes [Re(CO)3(N-RIm)2(L)](+) (N-RIm = N-alkylimidazole; L = N≡CtBu, C≡NtBu) selectively afforded alkylidenamido or iminoacyl derivatives, respectively, in which C-C coupling has occurred. Protonation of the latter complex leads to aminocarbene products.
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MEDLINE
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article