Design, synthesis, and evaluation of nonaqueous silylamines for efficient CO2 capture.
ChemSusChem
; 7(1): 299-307, 2014 Jan.
Article
em En
| MEDLINE
| ID: mdl-24203891
ABSTRACT
A series of silylated amines have been synthesized for use as reversible ionic liquids in the application of post-combustion carbon capture. We describe a molecular design process aimed at influencing industrially relevant carbon capture properties, such as viscosity, temperature of reversal, and enthalpy of regeneration, while maximizing the overall CO2 -capture capacity. A strong structure-property relationship among the silylamines is demonstrated in which minor structural modifications lead to significant changes in the bulk properties of the reversible ionic liquid formed from reaction with CO2 .
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Texto completo:
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Base de dados:
MEDLINE
Assunto principal:
Silanos
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Dióxido de Carbono
/
Líquidos Iônicos
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Aminas
Idioma:
En
Ano de publicação:
2014
Tipo de documento:
Article