{4-Chloro-N'-[(2-oxidonaphthalen-1-yl-κO)methyl-idene]benzohydrazidato-κ(2) N',O}di-methyl-tin(IV).
Acta Crystallogr Sect E Struct Rep Online
; 69(Pt 12): m688, 2013 Nov 30.
Article
em En
| MEDLINE
| ID: mdl-24454187
ABSTRACT
In the title complex, [Sn(CH3)2(C18H11ClN2O2)], the Sn(IV) ion is coordinated by two O atoms and an N atom from a 4-chloro-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal-bipyramidal geometry [Sn-O = 2.092â
(3) and 2.144â
(3)â
Å; Sn-N = 2.160â
(4)â
Å]. The dihedral angle between the naphthalene ring system and the benzene ring is 8.6â
(2)°. In the crystal, adjacent mol-ecules are linked by weak C-Hâ¯O hydrogen bonds, forming a chain along the b-axis direction.
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MEDLINE
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article