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{4-Chloro-N'-[(2-oxidonaphthalen-1-yl-κO)methyl-idene]benzohydrazidato-κ(2) N',O}di-methyl-tin(IV).
Cui, Jichun; Qiao, Yanling; Wang, Fei.
Afiliação
  • Cui J; College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.
  • Qiao Y; College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.
  • Wang F; College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online ; 69(Pt 12): m688, 2013 Nov 30.
Article em En | MEDLINE | ID: mdl-24454187
ABSTRACT
In the title complex, [Sn(CH3)2(C18H11ClN2O2)], the Sn(IV) ion is coordinated by two O atoms and an N atom from a 4-chloro-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal-bipyramidal geometry [Sn-O = 2.092 (3) and 2.144 (3) Å; Sn-N = 2.160 (4) Å]. The dihedral angle between the naphthalene ring system and the benzene ring is 8.6 (2)°. In the crystal, adjacent mol-ecules are linked by weak C-H⋯O hydrogen bonds, forming a chain along the b-axis direction.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2013 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2013 Tipo de documento: Article