Metal-organic proximity in a synthetic pocket.
J Am Chem Soc
; 136(8): 2966-9, 2014 Feb 26.
Article
em En
| MEDLINE
| ID: mdl-24512535
ABSTRACT
Proximity between a noninteractive organic substrate and a transition metal (trans-MCl2(PEt3)2; M = Pd or Pt) is achieved by their co-encapsulation within a synthetic cage, as revealed by X-ray crystallographic analysis and NOESY experiments. Through co-encapsulation with a Pd(II) complex, a terminal alkyne was activated within the cage to give a σ-alkynylpalladium complex.
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MEDLINE
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Ano de publicação:
2014
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Article