Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne species.

Callens, E; Abou-Hamad, E; Riache, N; Basset, J M

Callens, E; Abou-Hamad, E; Riache, N; Basset, J M.

Afiliação

Callens E; KAUST Catalyst Center, Physical Sciences and Engineering Division, King Abdullah University of Science and Technology, Thuwal, 23955-6900, Saudi Arabia. Emmanuel.callens@kaust.edu.sa Jean-Marie.Basset@kaust.edu.sa.

Chem Commun (Camb) ; 50(30): 3982-5, 2014 Apr 18.

Article em En | MEDLINE | ID: mdl-24609531

ABSTRACT

ABSTRACT

Extensive solid-state NMR analyses unambiguously determine the formation of silica supported W bis-methylidene methyl species by reaction of the corresponding methyl carbyne with trimethylphosphine or a cyclic olefin.

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2014 Tipo de documento: Article

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2014 Tipo de documento: Article