Functionalized graphene as a gatekeeper for chiral molecules: an alternative concept for chiral separation.
Angew Chem Int Ed Engl
; 53(37): 9957-60, 2014 Sep 08.
Article
em En
| MEDLINE
| ID: mdl-25044879
ABSTRACT
We propose a new method of chiral separation using functionalized nanoporous graphene as an example. Computational simulations based on density functional theory show that the attachment of a suitable chiral "bouncer" molecule to the pore rim prevents the passage of the undesired enantiomer while letting its mirror image through.
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MEDLINE
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En
Ano de publicação:
2014
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Article