Enantiomerically enriched tris(boronates): readily accessible conjunctive reagents for asymmetric synthesis.
J Am Chem Soc
; 136(46): 16140-3, 2014 Nov 19.
Article
em En
| MEDLINE
| ID: mdl-25387002
ABSTRACT
The catalytic enantioselective diboration of vinyl boronate esters furnishes chiral tris(boronates) in a selective fashion. Subsequent deborylative alkylation occurs in a diastereoselective fashion, both for intermolecular and intramolecular processes.
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1
Base de dados:
MEDLINE
Assunto principal:
Ácidos Borônicos
Idioma:
En
Ano de publicação:
2014
Tipo de documento:
Article