Activation-strain analysis reveals unexpected origin of fast reactivity in heteroaromatic azadiene inverse-electron-demand diels-alder cycloadditions.

Talbot, Austin; Devarajan, Deepa; Gustafson, Samantha J; Fernández, Israel; Bickelhaupt, F Matthias; Ess, Daniel H

Talbot, Austin; Devarajan, Deepa; Gustafson, Samantha J; Fernández, Israel; Bickelhaupt, F Matthias; Ess, Daniel H.

Afiliação

Talbot A; Department of Chemistry and Biochemistry, Brigham Young University, Provo, Utah 84602, United States.
Devarajan D; Department of Chemistry and Biochemistry, Brigham Young University, Provo, Utah 84602, United States.
Gustafson SJ; Department of Chemistry and Biochemistry, Brigham Young University, Provo, Utah 84602, United States.
Fernández I; Departamento de Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense, E-28040 Madrid, Spain.
Bickelhaupt FM; §Department of Theoretical Chemistry and Amsterdam Center for Multiscale Modeling (ACMM), VU University Amsterdam, De Boelelaan 1083, NL-1081 HV Amsterdam, The Netherlands.
Ess DH; â¥Institute for Molecules and Materials (IMM), Radboud University Nijmegen, Heyendaalseweg 135, NL-6525 AJ Nijmegen, The Netherlands.

J Org Chem ; 80(1): 548-58, 2015 Jan 02.

Article em En | MEDLINE | ID: mdl-25490250

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2015 Tipo de documento: Article

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2015 Tipo de documento: Article