Halogen-Bond-Assisted Guest Inclusion in a Synthetic Cavity.
Angew Chem Int Ed Engl
; 54(29): 8411-4, 2015 Jul 13.
Article
em En
| MEDLINE
| ID: mdl-26012524
ABSTRACT
The confined space inside a self-assembled cage enhanced halogen bonding (XB) between iodoperfluorocarbons (XB donors) and NO3(-) anions or H2O molecules (XB acceptors), as confirmed by NMR spectroscopy in solution and by X-ray crystallography in the solid state. The cavity also bound an XB donor-acceptor pair, C6F3I3 and C6H5NMe2, in a selective pairwise fashion.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2015
Tipo de documento:
Article