Synthesis of Diaryliodonium Salts Having Pentafluorosulfanylarenes and Their Application to Electrophilic Pentafluorosulfanylarylation of C-, O-, N-, and S-Nucleophiles.
Org Lett
; 17(12): 3038-41, 2015 Jun 19.
Article
em En
| MEDLINE
| ID: mdl-26023887
ABSTRACT
Novel reagents for the electrophilic introduction of pentafluorosulfanyl (SF5) arenes into target molecules are disclosed. Unsymmetrical diaryliodonium salts 1 having SF5-arenes were synthesized by a one-pot process from iodo-SF5-benzenes 2 in good yields. The SF5-aryliodonium salts 1 were found to be efficient for the electrophilic SF5-arylation of carbon and heterocentered nucleophiles to furnish the corresponding substituted SF5-arenes in good to high yields.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Oniocompostos
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Sais
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Hidrocarbonetos Fluorados
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Indicadores e Reagentes
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Iodo
Idioma:
En
Ano de publicação:
2015
Tipo de documento:
Article