Crystal structure of catena-poly[[di-aqua-cadmium(II)]-µ-3,3'-(1,3-phenyl-ene)diacrylato].
Acta Crystallogr E Crystallogr Commun
; 71(Pt 4): m91-2, 2015 Apr 01.
Article
em En
| MEDLINE
| ID: mdl-26029417
ABSTRACT
In the crystal of the title polymeric complex, [Cd(C12H8O4)(H2O)2] n , the Cd(II) cation, located on a twofold rotation axis, is coordinated by two water mol-ecules and chelated by two phenyl-enediacrylate anions (mpda) in a distorted octa-hedral geometry. The mpda anions bridge the Cd(II) cations, forming helical chains propagating along the c-axis direction. The mpba anion has twofold symmetry with two benzene C atoms located on the twofold rotation axis. In the crystal, O-Hâ¯O hydrogen bonds link the polymeric helical chains into a three-dimensional supra-molecular architecture.
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MEDLINE
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En
Ano de publicação:
2015
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Article