Probing Interfacial Water on Nanodiamonds in Colloidal Dispersion.
J Phys Chem Lett
; 6(15): 2909-12, 2015 Aug 06.
Article
em En
| MEDLINE
| ID: mdl-26267179
ABSTRACT
The structure of interfacial water layers around nanoparticles dispersed in an aqueous environment may have a significant impact on their reactivity and on their interaction with biological species. Using transmission soft X-ray absorption spectroscopy in liquid, we demonstrate that the unoccupied electronic states of oxygen atoms from water molecules in aqueous colloidal dispersions of nanodiamonds have a different signature than bulk water. X-ray absorption spectroscopy can thus probe interfacial water molecules in colloidal dispersions. The impacts of nanodiamond surface chemistry and concentration on interfacial water electronic signature are discussed.
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Base de dados:
MEDLINE
Assunto principal:
Água
/
Coloides
/
Nanodiamantes
Idioma:
En
Ano de publicação:
2015
Tipo de documento:
Article