Crystal structure of di-chlorido-bis-(1,3,4,5-tetra-methyl-1H-imidazol-2-ium-2-thiol-ate-κS)nickel(II).
Acta Crystallogr E Crystallogr Commun
; 71(Pt 8): m147, 2015 Aug 01.
Article
em En
| MEDLINE
| ID: mdl-26396777
ABSTRACT
In the mol-ecular structure of the title compound, [NiCl2(C7H12N2S)2], the Ni(II) atom has a distorted tetra-hedral geometry, coordinated by two Cl atoms [Ni-Cl= 2.2336â
(6)â
Å] and two thione S atoms [Ni-S= 2.3024â
(6)â
Å]. The angles at the Ni(II) cation, which lies on a twofold rotation axis, are Cl-Ni-Cl = 115.58â
(3)° and S-Ni-S = 94.55â
(3)°. All other angles at the central Ni(II) atom range from 109.46â
(2) to 112.96â
(2)°. The C-S-Ni angle is 99.91â
(6)°. The planes of two imidazolium rings make a dihedral angle of 70.56â
(6)°.
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MEDLINE
Idioma:
En
Ano de publicação:
2015
Tipo de documento:
Article