Your browser doesn't support javascript.
loading
Graphene oxide as a metal-free catalyst for oxidation of primary amines to nitriles by hypochlorite.
Primo, Ana; Puche, Marta; Pavel, Octavian D; Cojocaru, Bogdan; Tirsoaga, Alina; Parvulescu, Vasile; García, Hermenegildo.
Afiliação
  • Primo A; Instituto Universitario de Tecnología Química CSIC-UPV, Univ. Politécnica de Valencia, Avda/de los Naranjos s/n, 46022, Valencia, Spain. hgarcia@qim.upv.es.
  • Puche M; Instituto Universitario de Tecnología Química CSIC-UPV, Univ. Politécnica de Valencia, Avda/de los Naranjos s/n, 46022, Valencia, Spain. hgarcia@qim.upv.es.
  • Pavel OD; Department of Chemical Technology and Catalysis, University of Bucharest, Bucharest 030016, Romania.
  • Cojocaru B; Department of Chemical Technology and Catalysis, University of Bucharest, Bucharest 030016, Romania.
  • Tirsoaga A; Department of Chemical Technology and Catalysis, University of Bucharest, Bucharest 030016, Romania.
  • Parvulescu V; Department of Chemical Technology and Catalysis, University of Bucharest, Bucharest 030016, Romania.
  • García H; Instituto Universitario de Tecnología Química CSIC-UPV, Univ. Politécnica de Valencia, Avda/de los Naranjos s/n, 46022, Valencia, Spain. hgarcia@qim.upv.es.
Chem Commun (Camb) ; 52(9): 1839-42, 2016 Jan 31.
Article em En | MEDLINE | ID: mdl-26670136
ABSTRACT
Graphene oxide catalyzes oxidation by NaClO of primary benzyl and aliphatic amines to a product distribution comprising nitriles and imines. Nitriles are the sole product for long chain aliphatic amines. Spectroscopic characterization suggests that percarboxylic and perlactone groups could be the active sites of the process.
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article