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Cu(II)-catalyzed esterification reaction via aerobic oxidative cleavage of C(CO)-C(alkyl) bonds.
Ma, Ran; He, Liang-Nian; Liu, An-Hua; Song, Qing-Wen.
Afiliação
  • Ma R; State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, China and Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, China. heln@nankai.edu.cn.
  • He LN; State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, China and Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, China. heln@nankai.edu.cn.
  • Liu AH; State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, China and Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, China. heln@nankai.edu.cn.
  • Song QW; State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, China and Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, China. heln@nankai.edu.cn.
Chem Commun (Camb) ; 52(10): 2145-8, 2016 Feb 04.
Article em En | MEDLINE | ID: mdl-26698150
A novel Cu(II)-catalyzed aerobic oxidative esterification of simple ketones for the synthesis of esters has been developed with wide functional group tolerance. This process is assumed to go through a tandem sequence consisting of α-oxygenation/esterification/nucleophilic addition/C-C bond cleavage and carbon dioxide is released as the only byproduct.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article