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A Versatile and Scalable Strategy to Discrete Oligomers.
Lawrence, Jimmy; Lee, Sang-Ho; Abdilla, Allison; Nothling, Mitchell D; Ren, Jing M; Knight, Abigail S; Fleischmann, Carolin; Li, Youli; Abrams, Austin S; Schmidt, Bernhard V K J; Hawker, Michael C; Connal, Luke A; McGrath, Alaina J; Clark, Paul G; Gutekunst, Will R; Hawker, Craig J.
Afiliação
  • Lawrence J; Materials Research Laboratory and Departments of Materials, Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Lee SH; Materials Research Laboratory and Departments of Materials, Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Abdilla A; Materials Research Laboratory and Departments of Materials, Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Nothling MD; Materials Research Laboratory and Departments of Materials, Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Ren JM; Department of Chemical Engineering, University of Melbourne , Melbourne, Victoria, Australia.
  • Knight AS; Materials Research Laboratory and Departments of Materials, Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Fleischmann C; Materials Research Laboratory and Departments of Materials, Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Li Y; Materials Research Laboratory and Departments of Materials, Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Abrams AS; Materials Research Laboratory and Departments of Materials, Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Schmidt BV; Materials Research Laboratory and Departments of Materials, Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Hawker MC; Materials Research Laboratory and Departments of Materials, Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Connal LA; Max Planck Institute of Colloids and Interfaces , 14424 Potsdam, Germany.
  • McGrath AJ; Materials Research Laboratory and Departments of Materials, Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Clark PG; Department of Chemical Engineering, University of Melbourne , Melbourne, Victoria, Australia.
  • Gutekunst WR; Materials Research Laboratory and Departments of Materials, Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Hawker CJ; The Dow Chemical Company, Midland, Michigan 48674, United States.
J Am Chem Soc ; 138(19): 6306-10, 2016 05 18.
Article em En | MEDLINE | ID: mdl-27152711
ABSTRACT
A versatile strategy is reported for the multigram synthesis of discrete oligomers from commercially available monomer families, e.g., acrylates, styrenics, and siloxanes. Central to this strategy is the identification of reproducible procedures for the separation of oligomer mixtures using automated flash chromatography systems with the effectiveness of this approach demonstrated through the multigram preparation of discrete oligomer libraries (D = 1.0). Synthetic availability, coupled with accurate structural control, allows these functional building blocks to be harnessed for both fundamental studies as well as targeted technological applications.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Polímeros Idioma: En Ano de publicação: 2016 Tipo de documento: Article
Texto completo
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PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Polímeros Idioma: En Ano de publicação: 2016 Tipo de documento: Article