A new hydrophilic supramolecular photocatalyst for the production of H2 in aerobic aqueous solutions.
Chem Commun (Camb)
; 52(56): 8663-6, 2016 Jul 05.
Article
em En
| MEDLINE
| ID: mdl-27250778
ABSTRACT
Addition of sulfonated terminal ligands into a Ru,Rh,Ru photocatalyst has a significant impact on the excited-state properties of the complex. The hydrophilic photocatalyst demonstrates increased solubility and H2 production in aqueous solutions. H2 production is observed under aerobic conditions for the new complex, a stark contrast to the hydrophobic analog in organic solvents.
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MEDLINE
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En
Ano de publicação:
2016
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Article