A Short Synthesis of Aphanamol I in Both Racemic and Enantiopure Forms.
Chemistry
; 22(33): 11597-600, 2016 Aug 08.
Article
em En
| MEDLINE
| ID: mdl-27389970
ABSTRACT
A short synthesis of the biologically active sesquiterpene natural product (+)-aphanamol I in both racemic and enantiopure forms is reported. Key steps include a catalytic enantioselective conjugate addition, an oxidative radical cyclization, and a ring-expanding Claisen rearrangement.
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Base de dados:
MEDLINE
Assunto principal:
Sesquiterpenos
Idioma:
En
Ano de publicação:
2016
Tipo de documento:
Article