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Modular Synthesis of Arylacetic Acid Esters, Thioesters, and Amides from Aryl Ethers via Rh(II)-Catalyzed Diazo Arylation.
Best, Daniel; Jean, Mickaël; van de Weghe, Pierre.
Afiliação
  • Best D; Université de Rennes 1, UMR CNRS 6226, Institut des Sciences Chimiques de Rennes, Equipe PNSCM, UFR des Sciences, Biologiques et Pharmaceutiques, 2 Avenue du Prof Leon Bernard, Rennes F-35043 Cedex, France.
  • Jean M; Université de Rennes 1, UMR CNRS 6226, Institut des Sciences Chimiques de Rennes, Equipe PNSCM, UFR des Sciences, Biologiques et Pharmaceutiques, 2 Avenue du Prof Leon Bernard, Rennes F-35043 Cedex, France.
  • van de Weghe P; Université de Rennes 1, UMR CNRS 6226, Institut des Sciences Chimiques de Rennes, Equipe PNSCM, UFR des Sciences, Biologiques et Pharmaceutiques, 2 Avenue du Prof Leon Bernard, Rennes F-35043 Cedex, France.
J Org Chem ; 81(17): 7760-70, 2016 09 02.
Article em En | MEDLINE | ID: mdl-27465907
ABSTRACT
One-pot formation of arylacetic acid esters, thioesters, and amides via Rh(II)-catalyzed arylation of a Meldrum's acid-derived diazo reagent with electron-rich arenes is described. The methodology was used to efficiently synthesize an anticancer compound.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article