A study on the reaction of 16-dehydropregnenolone acetate with 2-aminobenzimidazole.
Steroids
; 117: 71-76, 2017 01.
Article
em En
| MEDLINE
| ID: mdl-27644145
The condensation of 16-dehydropregnenolone acetate with 2-aminobenzimidazole was studied. The polycyclic aromatic product was formed as a single regioisomer in a cascade reaction comprising addition, cyclization, autoxidation, and aromatization, in addition to the rearranged D-homo product. The reaction mechanism based on DFT calculations is proposed.
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Base de dados:
MEDLINE
Assunto principal:
Pregnenolona
/
Benzimidazóis
Idioma:
En
Ano de publicação:
2017
Tipo de documento:
Article