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KNH2-KH: a metal amide-hydride solid solution.
Santoru, Antonio; Pistidda, Claudio; Sørby, Magnus H; Chierotti, Michele R; Garroni, Sebastiano; Pinatel, Eugenio; Karimi, Fahim; Cao, Hujun; Bergemann, Nils; Le, Thi T; Puszkiel, Julián; Gobetto, Roberto; Baricco, Marcello; Hauback, Bjørn C; Klassen, Thomas; Dornheim, Martin.
Afiliação
  • Santoru A; Nanotechnology Department, Helmholtz-Zentrum Geesthacht Max-Planck Straße 1, 21502, Geesthacht, Germany. antonio.santoru@hzg.de and Department of Chemistry and NIS centre, University of Torino, V. Giuria 7, 10125, Torino, Italy.
  • Pistidda C; Nanotechnology Department, Helmholtz-Zentrum Geesthacht Max-Planck Straße 1, 21502, Geesthacht, Germany. antonio.santoru@hzg.de.
  • Sørby MH; Physics Department, Institute for Energy Technology (IFE), P.O. Box 40, NO-2027 Kjeller, Norway.
  • Chierotti MR; Department of Chemistry and NIS centre, University of Torino, V. Giuria 7, 10125, Torino, Italy.
  • Garroni S; Department of Chemistry and Pharmacy, University of Sassari, V. Vienna 2, 07100, Sassari, Italy.
  • Pinatel E; Department of Chemistry and NIS centre, University of Torino, V. Giuria 7, 10125, Torino, Italy.
  • Karimi F; Nanotechnology Department, Helmholtz-Zentrum Geesthacht Max-Planck Straße 1, 21502, Geesthacht, Germany. antonio.santoru@hzg.de.
  • Cao H; Nanotechnology Department, Helmholtz-Zentrum Geesthacht Max-Planck Straße 1, 21502, Geesthacht, Germany. antonio.santoru@hzg.de.
  • Bergemann N; Nanotechnology Department, Helmholtz-Zentrum Geesthacht Max-Planck Straße 1, 21502, Geesthacht, Germany. antonio.santoru@hzg.de.
  • Le TT; Nanotechnology Department, Helmholtz-Zentrum Geesthacht Max-Planck Straße 1, 21502, Geesthacht, Germany. antonio.santoru@hzg.de.
  • Puszkiel J; Nanotechnology Department, Helmholtz-Zentrum Geesthacht Max-Planck Straße 1, 21502, Geesthacht, Germany. antonio.santoru@hzg.de and Department of Physicochemistry of Materials, Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) y Centro Atómico Bariloche, Av. Bustillo km 9500, San
  • Gobetto R; Department of Chemistry and NIS centre, University of Torino, V. Giuria 7, 10125, Torino, Italy.
  • Baricco M; Department of Chemistry and NIS centre, University of Torino, V. Giuria 7, 10125, Torino, Italy.
  • Hauback BC; Physics Department, Institute for Energy Technology (IFE), P.O. Box 40, NO-2027 Kjeller, Norway.
  • Klassen T; Nanotechnology Department, Helmholtz-Zentrum Geesthacht Max-Planck Straße 1, 21502, Geesthacht, Germany. antonio.santoru@hzg.de.
  • Dornheim M; Nanotechnology Department, Helmholtz-Zentrum Geesthacht Max-Planck Straße 1, 21502, Geesthacht, Germany. antonio.santoru@hzg.de.
Chem Commun (Camb) ; 52(79): 11760-11763, 2016 Sep 27.
Article em En | MEDLINE | ID: mdl-27722247
We report for the first time the formation of a metal amide-hydride solid solution. The dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction among NH2- ions. The rotational properties of the high temperature polymorphs of KNH2 are thereby retained down to room temperature.
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Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article
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Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article