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Synthesis of a monomolecular anionic FLP complex.
Kyri, A W; Kunzmann, R; Schnakenburg, G; Qu, Z-W; Grimme, S; Streubel, R.
Afiliação
  • Kyri AW; Institut for Inorganic Chemistry of the Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhardt-Domagk-Strasse 1, 53121 Bonn, Germany. r.streubel@uni-bonn.de.
  • Kunzmann R; Institut for Inorganic Chemistry of the Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhardt-Domagk-Strasse 1, 53121 Bonn, Germany. r.streubel@uni-bonn.de.
  • Schnakenburg G; Institut for Inorganic Chemistry of the Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhardt-Domagk-Strasse 1, 53121 Bonn, Germany. r.streubel@uni-bonn.de.
  • Qu ZW; Mulliken Center of the Rheinische Friedrich-Wilhelms-Universität Bonn, Beringstr. 4, 53115 Bonn, Germany. grimme@thch.uni-bonn.de.
  • Grimme S; Mulliken Center of the Rheinische Friedrich-Wilhelms-Universität Bonn, Beringstr. 4, 53115 Bonn, Germany. grimme@thch.uni-bonn.de.
  • Streubel R; Institut for Inorganic Chemistry of the Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhardt-Domagk-Strasse 1, 53121 Bonn, Germany. r.streubel@uni-bonn.de.
Chem Commun (Camb) ; 52(91): 13361-13364, 2016 Nov 08.
Article em En | MEDLINE | ID: mdl-27782248
ABSTRACT
Despite intense research in FLP chemistry, nothing is known about monomolecular anionic FLPs and/or complexes thereof. Herein, synthesis and reaction of the first anionic FLP complex is described using [(OC)5W{(Me3Si)2HCP(H)OLi(12-crown-4)}], Cy2BCl and subsequent deprotonation by KHMDS. The obtained anionic FLP complex reacts readily with CO2 in a concerted manner.
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Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article
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Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article