Synthesis of a monomolecular anionic FLP complex.
Chem Commun (Camb)
; 52(91): 13361-13364, 2016 Nov 08.
Article
em En
| MEDLINE
| ID: mdl-27782248
ABSTRACT
Despite intense research in FLP chemistry, nothing is known about monomolecular anionic FLPs and/or complexes thereof. Herein, synthesis and reaction of the first anionic FLP complex is described using [(OC)5W{(Me3Si)2HCP(H)OLi(12-crown-4)}], Cy2BCl and subsequent deprotonation by KHMDS. The obtained anionic FLP complex reacts readily with CO2 in a concerted manner.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2016
Tipo de documento:
Article