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Observation of the chemical reaction equilibria of element 104, rutherfordium: solid-liquid extraction of Rf, Zr, Hf and Th with Aliquat 336 resin from HCl.
Yokokita, Takuya; Kasamatsu, Yoshitaka; Kino, Aiko; Haba, Hiromitsu; Shigekawa, Yudai; Yasuda, Yuki; Nakamura, Kouhei; Toyomura, Keigo; Komori, Yukiko; Murakami, Masashi; Yoshimura, Takashi; Takahashi, Naruto; Morita, Kosuke; Shinohara, Atsushi.
Afiliação
  • Yokokita T; Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. kasa@chem.sci.osaka-u.ac.jp.
  • Kasamatsu Y; Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. kasa@chem.sci.osaka-u.ac.jp.
  • Kino A; Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. kasa@chem.sci.osaka-u.ac.jp.
  • Haba H; Nishina Center for Accelerator-Based Science, RIKEN, Wako, Saitama 351-0198, Japan.
  • Shigekawa Y; Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. kasa@chem.sci.osaka-u.ac.jp.
  • Yasuda Y; Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. kasa@chem.sci.osaka-u.ac.jp.
  • Nakamura K; Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. kasa@chem.sci.osaka-u.ac.jp.
  • Toyomura K; Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. kasa@chem.sci.osaka-u.ac.jp.
  • Komori Y; Nishina Center for Accelerator-Based Science, RIKEN, Wako, Saitama 351-0198, Japan.
  • Murakami M; Nishina Center for Accelerator-Based Science, RIKEN, Wako, Saitama 351-0198, Japan.
  • Yoshimura T; Radioisotope Research Center, Osaka University, Suita, Osaka 565-0871, Japan.
  • Takahashi N; Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. kasa@chem.sci.osaka-u.ac.jp.
  • Morita K; Nishina Center for Accelerator-Based Science, RIKEN, Wako, Saitama 351-0198, Japan.
  • Shinohara A; Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. kasa@chem.sci.osaka-u.ac.jp.
Dalton Trans ; 45(47): 18827-18831, 2016 Nov 29.
Article em En | MEDLINE | ID: mdl-27853791
We successfully observed the equilibrium state of the chemical reactions for superheavy elements on a one-atom-at-a-time scale; we investigated the time dependence of the extraction behaviour of element 104, Rf. The distribution coefficient of Rf in 9 M HCl was found to be higher than those of its homologous elements, probably due to differences in the chloride complexation of Rf.
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Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article
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Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article