Asymmetric Strecker Reaction Arising from the Molecular Orientation of an Achiral Imine at the Single-Crystal Face: Enantioenriched l- and d-Amino Acids.

Miyagawa, Shinobu; Yoshimura, Koji; Yamazaki, Yusuke; Takamatsu, Naoya; Kuraishi, Tetsuya; Aiba, Shohei; Tokunaga, Yuji; Kawasaki, Tsuneomi

Miyagawa, Shinobu; Yoshimura, Koji; Yamazaki, Yusuke; Takamatsu, Naoya; Kuraishi, Tetsuya; Aiba, Shohei; Tokunaga, Yuji; Kawasaki, Tsuneomi.

Afiliação

Miyagawa S; Department of Materials Science, University of Fukui, Bunkyo, Fukui, 910-8507, Japan.
Yoshimura K; Department of Materials Science, University of Fukui, Bunkyo, Fukui, 910-8507, Japan.
Yamazaki Y; Department of Materials Science, University of Fukui, Bunkyo, Fukui, 910-8507, Japan.
Takamatsu N; Department of Materials Science, University of Fukui, Bunkyo, Fukui, 910-8507, Japan.
Kuraishi T; Department of Materials Science, University of Fukui, Bunkyo, Fukui, 910-8507, Japan.
Aiba S; Department of Materials Science, University of Fukui, Bunkyo, Fukui, 910-8507, Japan.
Tokunaga Y; Department of Materials Science, University of Fukui, Bunkyo, Fukui, 910-8507, Japan.
Kawasaki T; Department of Materials Science, University of Fukui, Bunkyo, Fukui, 910-8507, Japan.

Angew Chem Int Ed Engl ; 56(4): 1055-1058, 2017 01 19.

Article em En | MEDLINE | ID: mdl-28004489

Assuntos

Aminoácidos/química; Iminas/química; Aminoácidos/síntese química; Cristalização; Conformação Molecular; Nitrilas/síntese química; Nitrilas/química; Estereoisomerismo

Palavras-chave

amino acids; asymmetric amplification; chirality; enantioselectivity; structure elucidation

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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Aminoácidos / Iminas Idioma: En Ano de publicação: 2017 Tipo de documento: Article

Texto completo

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PubMed Links

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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Aminoácidos / Iminas Idioma: En Ano de publicação: 2017 Tipo de documento: Article