Selective Fluorimetric Detection of Primary Alkylamines by a Calix[6]arene Funnel Complex.
Chemistry
; 23(36): 8669-8677, 2017 Jun 27.
Article
em En
| MEDLINE
| ID: mdl-28370654
ABSTRACT
The association of host-guest and coordination chemistry was used to develop a fluorescent molecular sensor. A calix[6]arene bearing three imidazole arms at the small rim and three quinoline fluorophores at the large rim was synthesized and characterized. A two-step coordination sequence was observed upon addition of ZnII . The first ZnII center binds the tris-imidazole small rim site, leading only to a small perturbation of the fluorescence. In contrast, a large bathochromic shift is observed upon binding of the second ZnII center at the large rim as a result of the direct interaction of ZnII with the quinoline fluorophores. The system acts as a selective receptor for primary amines. Host-guest adduct formation could be identified by a shift and enhancement of the fluorescence emission that is dependent on the length and shape of the primary amine. This system constitutes a fluorescent reporter with a selective response among primary amines.
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MEDLINE
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En
Ano de publicação:
2017
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Article