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Surfactant 1-Hexadecyl-3-methylimidazolium Chloride Can Convert One-Dimensional Viologen Bromoplumbate into Zero-Dimensional.
Liu, Guangfeng; Liu, Jie; Nie, Lina; Ban, Rui; Armatas, Gerasimos S; Tao, Xutang; Zhang, Qichun.
Afiliação
  • Liu G; School of Materials Science and Engineering, Nanyang Technological University , Singapore 639798, Singapore.
  • Liu J; State Key Laboratory of Crystal Materials, Shandong University , Jinan, Shandong 250100, P. R. China.
  • Nie L; School of Materials Science and Engineering, Nanyang Technological University , Singapore 639798, Singapore.
  • Ban R; School of Materials Science and Engineering, Nanyang Technological University , Singapore 639798, Singapore.
  • Armatas GS; Department of Materials Science and Technology, University of Crete , 71003 Heraklion, Greece.
  • Tao X; State Key Laboratory of Crystal Materials, Shandong University , Jinan, Shandong 250100, P. R. China.
  • Zhang Q; School of Materials Science and Engineering, Nanyang Technological University , Singapore 639798, Singapore.
Inorg Chem ; 56(10): 5498-5501, 2017 May 15.
Article em En | MEDLINE | ID: mdl-28437099
ABSTRACT
A zero-dimensional N,N'-dibutyl-4,4'-dipyridinium bromoplumbate, [BV]6[Pb9Br30], with unusual discrete [Pb9Br30]12- anionic clusters was prepared via a facile surfactant-mediated solvothermal process. This bromoplumbate exhibits a narrower optical band gap relative to the congeneric one-dimensional viologen bromoplumbates.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article