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NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity.
Dhara, Debabrata; Vijayakanth, Thangavel; Barman, Milan Kr; Naik, Khevath Praveen Kumar; Chrysochos, Nicolas; Yildiz, Cem B; Boomishankar, Ramamoorthy; Schulzke, Carola; Chandrasekhar, Vadapalli; Jana, Anukul.
Afiliação
  • Dhara D; Tata Institute of Fundamental Research Centre for Interdisciplinary Sciences 21, Brundavan Colony, Narsingi, Hyderabad-500075, India. ajana@tifrh.res.in.
  • Vijayakanth T; Department of Chemistry, Indian Institute of Science Education and Research (IISER), Pune, Dr. Homi Bhabha Road, Pune 411008, India. boomi@iiserpune.ac.in.
  • Barman MK; Tata Institute of Fundamental Research Centre for Interdisciplinary Sciences 21, Brundavan Colony, Narsingi, Hyderabad-500075, India. ajana@tifrh.res.in.
  • Naik KPK; Tata Institute of Fundamental Research Centre for Interdisciplinary Sciences 21, Brundavan Colony, Narsingi, Hyderabad-500075, India. ajana@tifrh.res.in.
  • Chrysochos N; Institut für Biochemie, Ernst-Moritz-Arndt Universität Greifswald Felix-Hausdorff-Straße 4, D-17487 Greifswald, Germany. carola.schulzke@uni-greifswald.de.
  • Yildiz CB; Department of Medicinal and Aromatic Plants, University of Aksaray, Aksaray, Turkey. cemburakyildiz@aksaray.edu.tr.
  • Boomishankar R; Department of Chemistry, Indian Institute of Science Education and Research (IISER), Pune, Dr. Homi Bhabha Road, Pune 411008, India. boomi@iiserpune.ac.in.
  • Schulzke C; Institut für Biochemie, Ernst-Moritz-Arndt Universität Greifswald Felix-Hausdorff-Straße 4, D-17487 Greifswald, Germany. carola.schulzke@uni-greifswald.de.
  • Chandrasekhar V; National Institute of Science Education and Research, Bhimpur-Padanpur, Jatni, Khurda, Bhubaneswar-752050, Odisha, India and Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India. vc@iitk.ac.in.
  • Jana A; Tata Institute of Fundamental Research Centre for Interdisciplinary Sciences 21, Brundavan Colony, Narsingi, Hyderabad-500075, India. ajana@tifrh.res.in.
Chem Commun (Camb) ; 53(61): 8592-8595, 2017 Jul 27.
Article em En | MEDLINE | ID: mdl-28718477
A facile, straightforward synthesis of N-heterocyclic carbene (NHC)-stabilized 1-hydrosilaimine starting from a silicon(iv)-precursor is reported. It has been employed for the addition of an O-H bond of water under ambient conditions without any additional catalyst.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article