Going against the flow: Os(ii)-to-Ru(ii) energy transfer in rod-like polypyridyl chromophore.
Chem Commun (Camb)
; 53(76): 10496-10499, 2017 Sep 21.
Article
em En
| MEDLINE
| ID: mdl-28787049
ABSTRACT
The judicious design of a unique mixed-metal Ru-Os molecular rod led to the first photoinduced energy transfer from osmium-to-ruthenium in a polypyridyl complex. The absorbed light is directed from the osmium metal center to the peripheral ruthenium moieties, where only the low energy luminescence from the heteroleptic ruthenium phen-hpp complex was observed.
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MEDLINE
Idioma:
En
Ano de publicação:
2017
Tipo de documento:
Article