Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(iii) complex.
Dalton Trans
; 46(36): 12032-12035, 2017 Sep 28.
Article
em En
| MEDLINE
| ID: mdl-28853468
2-Acetylpyridine oxime esters are transformed into the corresponding α-oxygenated imines in an Ir(iii) complex under mild conditions, where the selective metal coordination of the imino group effectively promotes tautomerization of the oxime esters into the N-oxyenamines and the subsequent rearrangement.
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MEDLINE
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En
Ano de publicação:
2017
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Article