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Bis(stibahousene).
Lee, Vladimir Ya; Ota, Kei; Ito, Yuki; Gapurenko, Olga A; Sekiguchi, Akira; Minyaev, Ruslan M; Minkin, Vladimir I; Gornitzka, Heinz.
Afiliação
  • Lee VY; Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba , Tsukuba, Ibaraki 305-8571, Japan.
  • Ota K; Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba , Tsukuba, Ibaraki 305-8571, Japan.
  • Ito Y; Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba , Tsukuba, Ibaraki 305-8571, Japan.
  • Gapurenko OA; Institute of Physical and Organic Chemistry, Southern Federal University , Rostov on Don 344090, Russian Federation.
  • Sekiguchi A; Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba , Tsukuba, Ibaraki 305-8571, Japan.
  • Minyaev RM; Institute of Physical and Organic Chemistry, Southern Federal University , Rostov on Don 344090, Russian Federation.
  • Minkin VI; Institute of Physical and Organic Chemistry, Southern Federal University , Rostov on Don 344090, Russian Federation.
  • Gornitzka H; CNRS, LCC, Université de Toulouse, UPS, INPT , 205 Route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France.
J Am Chem Soc ; 139(39): 13897-13902, 2017 10 04.
Article em En | MEDLINE | ID: mdl-28892377
ABSTRACT
Strained hydrocarbons constitute one of the most prominent classes of organic compounds. Among them, bicyclo[2.1.0]pentene ("housene") derivatives represent a highly challenging and very attractive class. Although organic housenes have been known for more than five decades, there are still very few of them containing heavier main group elements. In this paper, we report on the two housene-type structures, novel monomeric stibahousene and dimeric bis(stibahousene). The bonding natures of both compounds were approached from both experimental and computational directions to reveal their peculiar structural features.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article