Aerobic Photooxidative Synthesis of ß-Alkoxy Monohydroperoxides Using an Organo Photoredox Catalyst Controlled by a Base.
Chem Asian J
; 13(4): 409-412, 2018 Feb 16.
Article
em En
| MEDLINE
| ID: mdl-29327427
ABSTRACT
Transition-metal-free synthesis of ß-alkoxy monohydroperoxides via aerobic photooxidation using an acridinium photocatalyst was developed. This method enables the synthesis of some novel hydroperoxides. The peroxide source is molecular oxygen, which is cost-effective and atomically efficient. Magnesium oxide plays an important role as a base in the catalytic system.
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MEDLINE
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En
Ano de publicação:
2018
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Article