A novel trigonal propeller-shaped hybrid tri-neodymium-polyoxometalate exhibiting single-molecule magnet behavior.
Dalton Trans
; 47(6): 1796-1800, 2018 Feb 06.
Article
em En
| MEDLINE
| ID: mdl-29354842
ABSTRACT
A trigonal propeller-shaped hybrid polyoxometalate (POM) (NH2Me2)3{[Nd(Mo4O13)(DMF)4]3(BTC)2}·8DMF (1; BTC = 1,3,5-benzenetricarboxylate) has been synthesized and structurally characterized. The planar {Mo4} segment is tailored from the precursor Lindqvist polyoxoanion [Mo6O19]2- firstly, and plays a key role in the reassembly of 1. Furthermore, the magnetic studies reveal that 1 shows single-molecule magnet (SMM) behavior.
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MEDLINE
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En
Ano de publicação:
2018
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Article