Your browser doesn't support javascript.
loading
Nonanuclear Ni(ii) complexes in a [1-7-1] formation derived from asymmetric multidentate ligands: magnetic and electrochemical properties.
Tsuji, Yasuhiro; Togo, Tatsuo; Mishima, Akio; Koshiyama, Tomomi; Ohba, Masaaki.
Afiliação
  • Tsuji Y; Department of Chemistry, Graduate School of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. ohba@chem.kyushu-univ.jp.
  • Togo T; Department of Chemistry, Graduate School of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. ohba@chem.kyushu-univ.jp.
  • Mishima A; Department of Chemistry, Graduate School of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. ohba@chem.kyushu-univ.jp.
  • Koshiyama T; Department of Chemistry, Graduate School of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. ohba@chem.kyushu-univ.jp.
  • Ohba M; Department of Chemistry, Graduate School of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. ohba@chem.kyushu-univ.jp.
Dalton Trans ; 47(12): 4036-4039, 2018 Mar 28.
Article em En | MEDLINE | ID: mdl-29424376
ABSTRACT
Nonanuclear Ni(ii) complexes, [Ni9(Ln)6(OH)6(H2O)6] (Ni9Ln, n = 1-4; H2Ln = 6-acetoacetyl-2-pyridinecarboxylic acid derivatives), were prepared via self-assembly using the asymmetric multidentate ligands H2Ln. A corner-sharing tetrahedron-type structure, [Ni7(µ3-OH)6]8+, and terminal mononuclear units constitute the nonanuclear structure in a [1-7-1] formation. The electrochemical and magnetic properties of Ni9Ln were modulated by the introduction of various substituents in H2Ln.
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article