Polyhomologation: Synthesis of Novel Polymethylene Architectures by a Living Polymerization of Dimethylsulfoxonium Methylide.
Angew Chem Int Ed Engl
; 37(10): 1391-1393, 1998 Jun 05.
Article
em En
| MEDLINE
| ID: mdl-29710896
ABSTRACT
Not conventional polymerization of ethylene, but rather the title reaction has allowed access to the ω-functionalized tertiary polymethylene alcohols 1. The ylide CH2 SOMe2 is the methylene source in this living polymerization, and the chain length can be set by the initial ratio of ylide to organoborane.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
1998
Tipo de documento:
Article