The O + NO( v) Vibrational Relaxation Processes Revisited.
J Phys Chem A
; 122(24): 5299-5310, 2018 Jun 21.
Article
em En
| MEDLINE
| ID: mdl-29792431
ABSTRACT
We have carried out a quasiclassical trajectory study of the O + NO( v) energy transfer process using DMBE potential energy surfaces for the ground-states of the 2A' and 2Aâ³ manifolds. State-to-state vibrational relaxation rate constants have been computed over the temperature range 298 and 3000 K and initial vibrational states between v = 1 and 9. The momentum-Gaussian binning approach has been employed to calculate the probability of the vibrational transitions. A comparison of the calculated state-to-state rate coefficients with the results from experimental studies and previous theoretical calculations shows the relevance of the 1 2Aâ³ potential energy surface to the title vibrational relaxation process.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2018
Tipo de documento:
Article