Cation-Modulated Rotary Speed in a Light-Driven Crown Ether Functionalized Molecular Motor.
Org Lett
; 20(13): 3715-3718, 2018 07 06.
Article
em En
| MEDLINE
| ID: mdl-29878791
ABSTRACT
The design and synthesis of an overcrowded-alkene based molecular motor featuring a crown ether integrated in its stator structure has been accomplished. The photostationary state ratios and rotational speed of this motor can be modulated by cation coordination to the crown ether moiety, which can be reversed upon the addition of a competing chelating agent, thus achieving a dynamic control over the rotational behavior of the motor.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2018
Tipo de documento:
Article