Improving Air-Stability and Performance of Bulk Heterojunction Polymer Solar Cells Using Solvent Engineered Hole Selective Interlayer.
Materials (Basel)
; 11(7)2018 Jul 05.
Article
em En
| MEDLINE
| ID: mdl-29976901
ABSTRACT
In bulk heterojunction polymer solar cells (BHJ-PSCs), poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonate) (PEDOTPSS) is the most commonly used hole selective interlayer (HSIL). However, its acidity, hygroscopic nature, and the use of indium tin oxide (ITO) etching can degrade the overall photovoltaic performance and the air-stability of BHJ-PSCs. Solvent engineering is considered as a facile approach to overcome these issues. In this work, we engineered the HSIL using ethanol (ET) treated PEDOTPSS to simultaneously enhance the photovoltaic performance properties and air-stability of the fabricated devices. We systematically investigated the influence of ET on the microstructural, morphological, interfacial characteristics of modified HSIL and photovoltaic characteristics of BHJ-PSCs. Compared with the BHJ-PSC with pristine PEDOTPSS, a significant enhancement of power conversion efficiency (~17%) was witnessed for the BHJ-PSC with PEDOTPSS-ET (v/v, 10.5). Consequently, the BHJ-PSC with PEDOTPSS-ET (v/v, 10.5) as HSIL exhibited remarkably improved air-stability.
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MEDLINE
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En
Ano de publicação:
2018
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Article